What is Addition Silicone?

Addition silicone, often shortened to “a-silicone”, is the most used impression material in restorative dentistry. It is widely regarded as the best impression material due to the advantages it holds over alternative materials. Also known as PVS (polyvinyl siloxane) or VPS (vinyl polysiloxane), addition silicone is an elastomeric impression material typically used for creating crowns, bridges, partial dentures and implants. A-silicone can take several different forms but will always follow the same chemical reaction of polymerisation and be presented as either a one-stage or two-stage paste-to-paste system.

Addition Silicone Composition

A-silicone Base Paste:

  • Polymethylhydrosiloxane (PMHS)
    undergoes cross-linking
  • Fillers (colloidal silica)
    controls viscosity

A-silicone Accelerator:

  • Polyvinyl siloxane cross-linking agent
  • Platinum salt catalyst
  • Fillers controls viscosity

What Are the Different Types of A-Silicone?

There are a few different types of addition silicone. These are based on their differing amounts of filler content. Filler content dictates the flow properties (viscosity) of each. The more filler, the thicker and less flowable the material will be.

Addition silicone materials come in as many five viscosities. Starting from the lowest viscosity to the highest, these are extra light body, light body, medium body (universal), heavy body and putty. The most used are medium body (35%-75% viscosity), heavy body (60%-70% viscosity) and light body (5%-15% viscosity), commonly referred to as wash.

Different types of addition silicones come with different setting (polymerisation) times. Addition silicones can be presented in double-barreled cartridges for use in an automix gun or as a base and catalyst putty.

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How is A-Silicone Used?

An a-silicone impression can be done using either a one-stage or two-stage paste-to-paste technique.

  • One-stage impression: Heavy-bodied a-silicone or putty is placed onto an impression tray. A layer of light-bodied a-silicone (wash) is then placed over it or directly onto the relevant teeth or both. The impression tray is then placed back into the patient’s mouth for the material to set.
  • Two-stage impression: A putty impression is recorded first, and after it has set it is relined with a thin layer of wash material. Two-stage impressions can be taken with or without a spacer.

Advantages of A-Silicone

Most Dimensionally Stable Impression Material

Addition Silicone creates no by-products when it sets. This is what makes it the most dimensionally stable impression material on the market. Also, because there is no shrinkage dental technicians can pour more than one model from one cast.

In comparison, condensation silicone produces an alcohol by-product that can cause the impression to shrink and alginate is susceptible to both imbibition (swelling) and syneresis (shrinking).

Best Fine Detail

Addition silicones provide very precise impressions with the best fine detail of any material.

This makes it the ideal choice for final impressions and ensuring the end product fits perfectly in the mouth of the patient.

Most Time to Pour

An a-silicone impression can be poured with gypsum as long as 60 minutes after setting. Its excellent stability means the impression could probably keep its shape for days before it needed pouring.

By comparison, alginate impressions should be poured with gypsum within 10 minutes and condensation silicone (c-silicone) within 30 minutes.

High Patient Acceptance

Addition silicone does not have an unpleasant taste or smell.

It also has a very short setting time, as quick as 2 minutes 30 seconds for fast-set varieties. This means the impression tray does not have to stay as long in the patient’s mouth.

Disadvantages of A-Silicone


  • Cost
  • Inhibited by the sulphur in latex gloves and rubber dam, so non-latex gloves and dams should be used if necessary
  • Hydrophobic so requires excellent moisture control